1. Match List-1 with List-II.

 

Choose the correct answer from the options given below: 

(a) (A)-(III), (B)-(IV), (C)-(1), (D)-(II)

(b) (A)-(1), (B)-(II), (C)-(III), (D)-(IV) 

(c) (A)-(IV), (B)-(UI), (C)-(II), (D)-(I)

(d) (A)-(II), (B)-(III), (C)-(1), (D)-(IV) 

ANS A

2. A + B → Nylon 6, 6 

Predict A and B: 

(a) Ethylene glycol + adipic acid

(b) Pentamethylene diamine + adipic acid 

(c) Hexamethylene amine + tartaric acid

(d) Hexamethylene diamine + adipic acid

ANS D

3. Which of the following compounds is the most acidic?

ANS C
ANS A

5. Which of the following hormones is also known as fight or flight hormone? 

(a) Adrenaline

(b) Androgens

(c) Thyroxine         

(d) Insulin

ANS A

6. Match List-I with List-II. 

 

Choose the correct answer from the options given below: 

(a) (A)-(II), (B)-(III), (C)-(IV), (D)-(I) 

(b) (A)-(I), (B)-(II), (C)-(IV), (D)-(III) 

(c) (A)-(III), (B)-(IV), (C)-(I), (D)-(II) 

(d) (A)-(II), (B)-(III), (C)-(1), (D)-(IV)

ANS B

7. Which of the following is the correct range of critical micelle concentrations (CMC) for soaps? 

(a) 102 to 104 mol/L

(b) 105 to 10-8 mol/L 

(c) 10-4 to 10-3 mol/L

(d) 10 to 10-3 mol/L 

ANS C
8. Which of the following is an example of negatively charged sol? 

(a) A12 O2 . Н2O

(b) As2 S3

(c) TiO2                 

(d) Blood

ANS D
9. Identify incorrect statement about H2-O2 fuel cell from the following: 

(a) At cathode O2 is reduced to OH- 

(b) At anode H2 is oxidised to form water 

(c) The cell runs continuously even if reactants are not supplied 

(d) Water is formed as a by product

ANS C
10. The correct statement about 4f-series elements is : 

(a) Paramagnetism falls to minimum in Nd. 

(b) Lu3+ ions are bright green in aqueous solution. 

(c) Promethium is an artificially synthesised 4f series element. 

(d) Absorption bands of Lanthanides are broad. 

 ANS C
11. Which of the following has the highest flocculating power? 

(a) [Fe(CN)6]4-

(b) PO43- 

(c) SO42--               

(d) Cl
ANS A

12. Match List-I with List-II.

 

Choose the correct answer from the options given below: 

(a) (A)-(II), (B)-(III), (C)-(IV), (D)-(1) 

(b) (A)-(I), (B)-(IV), (C)-(II), (D)-(II) 

(c) (A)-(II), (B)-(IV), (C)-(III), (D)-(1) 

(d). (A)-(1), (B)-(III), (C)-(IV), (D)-(I)

ANS C

13. Match List-I with List-II.

 

Choose the correct answer from the options given below: 

(a) (A)-(I), (B)-(III), (C)-(IV), (D)-(II) 

(b) (A)-(III), (B)-(IV), (C)-(I), (D)-(II) 

(c) (A)-(IV), (B)-(I), (C)-(III), (D)-(II) 

(d) (A)-(I), (B)-(IV), (C)-(II), (D)-(II)

ANS B
14. Which of the following reagents, are used for denaturation of alcohol? 

(a) CuSO4 and pyridine 

(b) FeSO4 and CHCI3

(c) CH3OH and pyridine 

(d) CuSO4 and freon
ANS C

15. Which of the following is the correct formula of a colligative property?

ANS C

16. The vapour pressure of pure Benzene is 0.900 bar. If a non-volatile electrolytic solid is added, vapour pressure of the solution becomes 0.200 bar. If the number of moles of solute is I and solvent is 2 respectively in solution, what is the value of van't Hoff factor (i)? 

(a) 2.33     

(b) 0.56  

(c) 1.56     

(d) 2.00 

ANS A
17. Which of the following alkyl halides will undergo SN2 reaction most readily? 

(a) 1-Bromo-2,2-dimethylpropane

(b) 1-Bromo-2-methylbutane 

(c) 1-Bromobutane 

(d) 1-Bromo-3-methylbutane

ANS C

18. Match List-I with List-II.

Choose the correct answer from the options given below: 

(a) (A)-(I), (B)-(II), (C)-(III), (D)-(IV) 

(b) (A)-(IV), (B)-(III), (C)-(II), (D)-(I) 

(c) (A)-(III), (B)-(II), (C)-(I), (D)-(IV) 

(d) (A)-(III), (B)-(IV), (C)-(II), (D)-(I)

ANS B

19. 19. For the reaction, R→ P, the log ([R0]/[R]) verses time(t) plot is given below. What is the order of reaction and what are the units of rate constant?

 

(a) Zero order, s-1 

(b) First order, s-1 

(c) Second order, mol-1 L s-1 

(d) Zero order, mol L-1 s-1

ANS B
20. An analysis of iron oxide shows that its formula is Fe1.9O3. What percentages of iron exists as Fe3+ and Fe4+ ions: 

(a) Fe3+ = 82.98% and Fe4+  =17.02% 

(b) Fe3+ = 84.21% and Fe4+ 15.79% 

(c) Fe3+ = 15.79% and Fe4+: = 84.21% 

(d) Fe3+= 17.02% and Fe4+ = 82.98%
ANS B

21. 

The compound B.is 

(a) Acetanilide 

(b) Benzonitrile 

(c) Benzamide 

(d) Benzene

ANS B

22.Match List-I with List-II.

(a) (A)-(IV), (B)-(III), (C)-(N, (D)-(M)

(b) (A)-(IV), (B)-(III), (C)-(II), (D)-(I)

(c) (A)-(III), (B)-(1), (C)-(IV), (D)-(II) 

(d) (A)-(III), (B)-(1), (C)-(II), (D)-(IV)

ANS A
23. The amount of radioactive substance left after 75 hrs, when 100 g of it is taken initially, provided its half life is 25 minutes, will be: 

(a) 12.5 g

(b) 6.25 g

(c) 1.5625 g

(d) 3.125 g

ANS A

24.Match List-I with List-II.

Choose the correct answer from the options given below : 

(a) (A)-(IV), (B)-(II), (C)-(II), (D)-(I) 

(b) (A)-(IV), (B)-(III), (C)-(I), (D)-(II)

(c) (A)-(1), (B)-(III), (C)-(IV), (D)-(II) 

(d) (A)-(1), (B)-(II), (C)-(IV), (D)-(II)

ANS B
25. Arrange the following compounds in decreasing order of acidity: 

(A) o-cresol 

(C) m-nitrophenol 

(E) Ethanol 

(B) Phenol 

(D) o-nitrophenol 

Choose the correct answer from the options given below: 

(a) D>B>C>E>A   

(b) E>A>B>C>D 

(c) C>D>A>B>E    

(d) D>C>B>A>E

ANS D

26. Match List-1 with List-II.

Choose the correct answer from the options given below: 

(a) (A)-(IV), (B)-(II), (C)-(I), (D)-(II) 

(b) (A)-(I), (B)-(II), (C)-(III), (D)-(IV) 

(c) (A)-(III), (B)-(IV), (C)-(II), (D)-(I) 

(d) (A)-(II), (B)- (III), (C)-(IV), (D) (I)

ANS B
27. In which of the following cases there is a change in -oxidation number? 

(a) Aqueous solution of CrO2-4 acidified 

(b) SO2 gas is passed through acidified Cr2 O2-7 solution 

(c) Cr2 O2-7 solution is made alkaline 

(d) CrO2Cl2 is dissolved in NaOH 

ANS B

28. The cell ZnZn2+(1M)||Cu2+(1 M) Cu. (E0 cell  =1.10V) was allowed to be completely discharged at 298 K. The relative concentration of Zn2+/Cu2+ is: 

(a) 9.65 x 104

(b) Antilog 24.8 

(c) 37.7

(d) 1037.3 

ANS D

29. Match List-1 with List-II.

Choose the correct answer from the options given below: 

(a) (A)-(I), (B)-(II), (C)-(III), (D)-(IV) 

(b) (A)-(IV), (B)-(III), (C)-(I), (D)-(II) 

(c) (A)-(III), (B)-(IV), (C)-(II), (D)-(I) 

(d) (A)-(II), (B)-(II), (C)-(IV), (D)-(I) 

ANS A
30. Which of the following reaction has fractional order with respect to one of the reactant? 

(a) 2NO(g) + O2(g) → 2NO2(g) 

(b) CHC13 + Cl2 → CCl4 + HCI 

(c) CH3 COO C2H5 + H2O → CH3COOH+C2H5OH 

(d) CH3 COO C2H5 + NaOH → CH3COONa+C2H5OH
ANS B

31. Identify the name reaction given below

(a) Gattermann Reaction 

(b) Sandmeyer Reaction 

(c) Gattermann - Koch Reaction 

(d) Dow's Process

ANS A

32. Out of the following which will not undergo SN1 reaction 

pathway: 

(a) 1-Chloro-1,1,1-triphenylmethane 

(b) 2-iodo-2-methylpropane 

(c) 1-Bromo-3,3-dimethylbutane 

(d) 3-Bromoprop-1-ene

ANS C

33. Which of the following is an example of minimum boiling azeotrope? 

(a) Phenol and aniline

(b) Chloroform and acetone 

(c) Nitric acid and water

(d) Ethanol and acetone

ANS D

34. Match List-I with List-II.

Choose the correct answer from the options given below: 

(a) (A)-(I), (B)-(II), (C)-(IV), (D)-(II) 

(b) (A)-(1), (B)-(III), (C)-(II), (D)-(IV) 

(c) (A)-(IV), (B)-(III), (C)-(1), (D)-(II) 

(d) (A)-(III), (B)-(II), (C)-(IV), (D)-(1)

ANS C
35. Glucose on reaction with bromine water forms gluconic 

acid which confirms the presence of: 

(a) -COOH group 

(b) –CHO group 

(c) Five-OH groups 

(d) Ketonic group

ANS B

36. The correct bond order for carbon-oxygen bond in following metal carbonyls 

[Cr(CO)6], [V(CO)6]-, [ Mn(CO)6]+ is:  

(a) [V(CO)6]-  < [Cr(CO)6] < [ Mn(CO)6]+ 

(b) [V(CO)6] ̄ = [Cr(CO)6] = [ Mn(CO)6]+ 

(c) [ Mn(CO)6]+< [Cr(CO)6] <  [V(CO)6]- 

(d) [Cr(CO)6] < [V(CO)6] ̄ < [ Mn(CO)6]+

ANS B

37. The magnetic nature of elements depends on the presence of unpaired electrons. Identify the configuration of transition elements which shows highest magnetic moment: 

(a) 3d7

(b) 3d6

(c) 3d8

(d) 3d2

ANS B

38. 

Choose the correct answer from the options given 

below : 

(a) (A)-(III), (B)-(II), (C)-(IV), (D)-(I) 

(b) (A)-(III), (B)-(I), (C)-(IV), (D)-(II) 

(c) (A)-(II), (B)-(III), (C)-(IV), (D)-(I) 

(d) (A)-(IV), (B)-(III), (C)-(II), (D)-(I)

ANS A

39. Match List-I with List-II.

Choose the correct answer from the options given 

below: 

(a) (A)-(I), (B)-(II), (C)-(III), (D)-(TV) 

(b) (A)-(IV), (B)-(III), (C)-(II), (D)-(I)  

(c) (A)-(II), (B)-(III), (C)-(I), (D)-(IV) · 

(d) (A)-(III), (B)-(IV), (C)-(II), (D)-(I)

ANS D
40. Sol Charge Present

(A) Blood   - positive

(B) Congo red   - positive

(C) Gum    - negative 

(D) Gold sol   - positive

(E) Fe(OH)3 sol - negative 

Choose the correct answer from the options given below: 

(a) (A) and (C) only 

(b) (B) and (D) only 

(c) (B) and (E) only 

(d) (C) only

ANS D
Answer the following questions on basis of the passage given below: (Q.41 to Q.45) 

Organic compounds containing carbon-oxygen double bonds are called carbonyl compounds. These are highly polar molecules. Hence, their boiling points are higher than hydrocarbons and ethers. Aldehydes can be prepared from dehydrogenation or oxidation of alcohols and by reduction of acyl halides. Ketones are prepared by oxidation of secondary alcohols or by hydration of alkynes etc. Aldehydes and ketones undergo nucleophilic addition reaction with the number of nucleophiles such as HCN, NaHSO3 ammonia derivatives: Carboxylic acids are prepared by the oxidation of primary alcohols, aldehydes and alkenes, by hydrolysis of nitriles. Carboxylic acids are more acidic than alcohols and phenols.

41. The product (A) is :

ANS B

Answer the following questions on basis of the passage given below: (Q.41 to Q.45) 

Organic compounds containing carbon-oxygen double bonds are called carbonyl compounds. These are highly polar molecules. Hence, their boiling points are higher than hydrocarbons and ethers. Aldehydes can be prepared from dehydrogenation or oxidation of alcohols and by reduction of acyl halides. Ketones are prepared by oxidation of secondary alcohols or by hydration of alkynes etc. Aldehydes and ketones undergo nucleophilic addition reaction with the number of nucleophiles such as HCN, NaHSO3 ammonia derivatives: Carboxylic acids are prepared by the oxidation of primary alcohols, aldehydes and alkenes, by hydrolysis of nitriles. Carboxylic acids are more acidic than alcohols and phenols.

42. The correct increasing order of acidic strength is :

ANS C
Answer the following questions on basis of the passage given below: (Q.41 to Q.45) 

Organic compounds containing carbon-oxygen double bonds are called carbonyl compounds. These are highly polar molecules. Hence, their boiling points are higher than hydrocarbons and ethers. Aldehydes can be prepared from dehydrogenation or oxidation of alcohols and by reduction of acyl halides. Ketones are prepared by oxidation of secondary alcohols or by hydration of alkynes etc. Aldehydes and ketones undergo nucleophilic addition reaction with the number of nucleophiles such as HCN, NaHSO3 ammonia derivatives: Carboxylic acids are prepared by the oxidation of primary alcohols, aldehydes and alkenes, by hydrolysis of nitriles. Carboxylic acids are more acidic than alcohols and phenols.

43. The correct sequence of reagents for the conversion of  3-nitrobromobenzene to 3-nitrobenzoic acid is: 

(a) Mg/ether, CO2, H3O+

(b) KCN, LiAHH4, NaOH 

(c) KMnO4/OH ̄, dil.H2SO4, CO2/H+

(d) AgNO3, (Ammoniacal), CO2, H3O+

ANS A
Answer the following questions on basis of the passage given below: (Q.41 to Q.45) 

Organic compounds containing carbon-oxygen double bonds are called carbonyl compounds. These are highly polar molecules. Hence, their boiling points are higher than hydrocarbons and ethers. Aldehydes can be prepared from dehydrogenation or oxidation of alcohols and by reduction of acyl halides. Ketones are prepared by oxidation of secondary alcohols or by hydration of alkynes etc. Aldehydes and ketones undergo nucleophilic addition reaction with the number of nucleophiles such as HCN, NaHSO3 ammonia derivatives: Carboxylic acids are prepared by the oxidation of primary alcohols, aldehydes and alkenes, by hydrolysis of nitriles. Carboxylic acids are more acidic than alcohols and phenols.

44. Which of the following is most reactive towards nucleophilic addition reaction? 

(a) Butanone

(b) Propanone 

(c) Ethanal

(d) Propanal

ANS C
Answer the following questions on basis of the passage given below: (Q.41 to Q.45) 

Organic compounds containing carbon-oxygen double bonds are called carbonyl compounds. These are highly polar molecules. Hence, their boiling points are higher than hydrocarbons and ethers. Aldehydes can be prepared from dehydrogenation or oxidation of alcohols and by reduction of acyl halides. Ketones are prepared by oxidation of secondary alcohols or by hydration of alkynes etc. Aldehydes and ketones undergo nucleophilic addition reaction with the number of nucleophiles such as HCN, NaHSO3 ammonia derivatives: Carboxylic acids are prepared by the oxidation of primary alcohols, aldehydes and alkenes, by hydrolysis of nitriles. Carboxylic acids are more acidic than alcohols and phenols.

45. The product (X) is:

ANS D

46. Single bond is not formed by two atoms of : 

(a) P-P

(b) N-N

(c) As-As         

(d) Sb - Sb 

ANS B

47. Maximum covalency of Nitrogen is: 

(a) 2

(b) 3

(c) 4 

(d) 5 

ANS C

48. The Nitrogen family show reducing characters. Least basic amongst the following is: 

(A) SbH3

(B) BiH3

(C) NH3

(D) PH3

Choose the correct answer from the options given below: 

(a) (C) only

(b) (A) only

(c) (B) only

(d) (D) only 

ANS C

49. Most stable hydride amongst the following is : 

(A) NH3

(B) PH3

(C) AsH3

(D) SbH3

(E) BiH3

Choose the correct answer from the options given below: 

(a) (A) only

(b) (B) only

(c) (C) & (D) only

(d) (D) & (E) only 

ANS D

50. Brown ring in nitrates test is formed when: 

(a) Fe2+ oxidises

(b) Fe3+ reduces

(c) NO3- oxidises

(d) HNO3 oxidises

ANS A